In a small saucepan, combine the citrus zest, cinnamon stick, coriander seeds, nutmeg, allspice, cloves, ginger, tamarind pod if using, water, sugar, and brown sugar.Bring to a gentle simmer over medium-low heat. Simmer for 15 to 20 minutes, stirring occasionally, until the sugar is fully dissolved and the mixture smells warm and cola-like.Remove from heat and strain through a fine-mesh strainer into a jar. Press lightly on the solids to extract the liquid, but do not force pulp through.Stir in the vanilla extract.Let cool completely before using.