Place both chocolate chips in a bowl over a pot of hot water on medium-low heat. Stir in the hot coffee and continue stirring until the chocolate has melted; turn off the heat and let sit until needed.
Sift the cocoa powder and flour together, set aside
Beat the cream cheese for 2 to 3 minutes with a hand or stand mixer until fluffy.
Add both sugars and beat for 2 to 3 minutes until the sugar is well incorporated.
Add eggs and yolks one at a time, mixing well after each addition.
Add in vanilla, sour cream, and buttermilk, mixing well.
Add in the sifted flour and cocoa powder and mix well.
Add in the melted chocolate and mix well.
Pour batter over crust.
Wrap the bottom of the pan in plastic wrap, then foil over the plastic wrap, and place the cake pan in another deep pan,
Place in the oven and pour hot water halfway up the cake pan.
Bake for 70 minutes.
The cheesecake is done when the sides are set, but the center is still slightly jiggly.
Remove from the oven onto a wire rack and let cook completely.
Refrigerate overnight.